Tuesday, May 24, 2011

Alicyclics & Aromatics

  • Carbon chains can form two types of closed loops
  • Alicyclics are loops usually made with single bonds
  • If the parent chain is a loop standard naming rules apply with one addition
Cyclopentane
  • There are three different ways to draw organic compounds

Condensed Structural Diagram

Complete Structural Diagram

Line Diagram
  • Numbering can start anywhere and go clockwise and counterclockwise on the loop but side chain numbers must be the lowest possible
EXAMPLES:
 1,1 dimethyl cyclobutane

1,3 diethyl cyclohexane

  • Loops can also be a sidechain
  • Same rules apply but the side chain is given a cyclo-prefix

    2 cyclobutane octane
    or
    2 methyl 3 cyclopropyl 1 pentene
Aromatics:
  • Benzene (C6H6) is a cyclic hydrocarbon with unique bonds between the carbon atoms
    Structurally it can be drawn with alternating double bonds



    or with a circle in the middle


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