Thursday, May 26, 2011

(TG) Carboxylic Acids, Alcohols and Esters!

CARBOXYLIC ACIDS


  •  A functional group formed by a doubled bonded O and an OH at the end of a Carbon chain
  • Standard rules apply to naming, but change the parent chain ending to -oic acid
  • The simplest carboxylic acid is methanoic acid



Examples! Name these compounds: 


http://www.chemguide.co.uk/basicorg/acidbase/ethanoicacid.GIF            (ethanoic acid, or commonly known as acetic acid.)




     (butanoic, or butyric acid)

Now, draw THESE compounds:

Propanoic acid:  









Pentanoic acid:






Now heres an extra tricky carboxylic acid that every chemist should know:

Benzenoic Acid:






 Great job! Now you're a pro... So lets move on to alcohols.... (dont get TOO excited high school students)


ALCOHOLS

  • Alcohols are the functional group that contain OH's as side chains
  • There can be OH's on any part of the side chain
  • There can be multiple OH's coming off the main chain, and when this happens you use the prefixes di tri tetra etc. (example) methadiol, butatriol etc
  • All standard naming rules apply!
Methanol:













Now here are some examples for you try out!: NAME THESE ALCOHOLS:

    Ethanol



                   Ethanediol



DRAW THESE:


propanetriol: 




butanediol:





Here again is a super tricky one when benzene becomes an alcohol!

PHENOL:








great work... now lets move on to our final topic ESTERS!

ESTERS!

  • Esters first off, are not to be confused with ethers.
  • An ester has 2 chains separated by an O, and then one chain right next to the O has a double bonded O on the first C
  • Esters are formed when you add carboxylic acids and alcohols together but we'll get into that after we do the basics
  • Name the chain without the double bonded O with an -yl ending, and the one with the double O with an -oate ending.
Methyl Methanoate:







Now that you've seen what it looks like, go ahead and name these:

      methyl ethanoate


  ethyl ethanoate



Draw these!

propyl ethanoate:




ethyl propanoate:




\








and finally, the finale. ESTERFICATION: when a carboxylic acid and an alcohol mix!








Here is a basic explanation. The 2 H's and O form water, and the remainder form the Ester!
Now do these esterfication processes!






   GOOD JOB GUYS!


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